Sum the values in s for each label in the first level (totals for A, B, C).
Input
A 0 0
1 1
2 2
3 3
4 4
..
C 5 25
6 26
7 27
8 28
9 29
Length: 30, dtype: int64
Output
A 45
B 145
C 245
dtype: int64